Notark Corp

Cation and Proton Exchange Polymers

Proton exchange membranes (PEMs) and cation exchange membranes (CEMs) are special materials that selectively allow the passage of positively charged ions (cations) while blocking negatively charged ions (anions) and gases. Proton exchange membranes are specifically designed to conduct protons (H ions) and are most commonly used in fuel cells (PEMFCs), where they play a critical role in enabling electrochemical reactions that convert hydrogen and oxygen into electricity. Cation exchange membranes, while similar in function, are broader in scope and can transport a variety of cations, including sodium, potassium, and calcium ions. They are widely used in applications such as water purification, electrodialysis, redox flow batteries, and other electrochemical processes where selective ion transport is essential. These membranes are integral to enabling clean energy systems and efficient chemical separations.

The TuffPEM Advantage-Distinctive Microstructure

Microstructure of Pentablock Copolymer by TEM

Reconstructed 3-dimensional Transmission Electron Microscopy image of pentablock ion conducting polymer. Image shows channels that run across depth (Z-axis), providing superior ionic conductivity.

Small Angle Xray Scattering (SAXS) comparing TuffPEM20 and Nafion 117

*Data from Argonne National Lab

Small angle X-ray scattering data for TuffPEM membrane compared with Nafion 117. The location of the primary peak (q*) in each SAXS profile relates to the characteristic spacing (D=2π/q*) of the morphology. Microdomain periodicities are measured for Nafion 117 and TuffPEM20 are 14.0nm and 41.4nm respectively. Larger domain spacing support high proton conductivity of TuffPEM.

Unique microstructure of TuffPEM polymer film enables high ionic conductivity

TuffPEM Key Attributes

Low Cost

  • TuffPEM offer up to 90% reduction in cost vs PFSA (perfluorinated sulfonic acid) membranes
  • Cost reduction is achieved by using commercially available monomers and well-established commercial scale manufacturing process

Performance

  • Higher ionic conductivity than PFSA membranes such as Nafion®
  • Ion and Hydrogen Cross-over: Lower ion and Hydrogen cross-over than Nafion®
  • Low swell in water: Crosslinking technology helps reduce swell

Fluorine Free

  • TuffPEM membranes do not use or contain fluorine based raw materials eliminating potential concerns associated with perfluoro chemicals as “forever chemicals”

Design Flexibility

  • TuffPEM grades are available in a wide range of IECs from 1.0 to 2.8 meq/g
  • TuffPEM grades can be optimized for specific application needs

availability

  • TuffPEM grades are available at commercial scale with capacity to produce millions of square meters per year in rolls of up to 1m wide.

TuffPEM offers commercial scale, high performance, fluorine-free ion conducting polymers (membranes and ionomers) that are up to 90% lower in cost vs alternative PEMs

TuffPEM Polymer and Membrane Grades

TuffPEM Polymer and Ionomer Grades

TuffPEM Polymer Grades are available in:

  • Solid (crumbs)
  • 3,000cP solution in (Toluene – Propanol)
  • TuffPEM polymers can be crosslinked in casting step

TuffPEM Polymer and Ionomer Grades

* ‘xx’ relates to polymer grade and its IEC. Different configurations are available upon request, with minimum order quantity requirements.

TuffPEM Membrane Samples Availability in Roll-to-Roll form

Polymer Membrane Type Membrane Thickness Comment
TuffPEM 20 Free standing 10–50 um Coating over lubricated PET substrate
TuffPEM 20 PBX5 Free standing 10–50 um Coating over lubricated PET substrate
TuffPEM 20 CPBX5 Composite 15–30 GSM Coating over microporous substrate

TuffPEM 20

TuffPEM 20PBX5

TuffPEM 20CPBX5